ORGANIZED SYSTEMS GROUP - G.S.O.

PUBLICACIONES / PUBLICATIONS


Artículos de investigación / Research papers

-Papers 2017-

On the Design of a Versatile Ionic Liquid, AOBH-DEHP, which Can Be Used As a New Molecular Probe to Investigate Supramolecular Assemblies. Matías A. Crosio, Juana J. Silber, R. Darío Falcone, N. Mariano Correa  Dyes and Pigments 2017, 138, 68-76.

Unique Catanionic Vesicles as a Potential “Nano-Taxi” for Drug Delivery System. In Vitro and In Vivo Biocompatibility Evaluation. S. Stagnoli; M. A. Luna; C. C. Villa; F. Alustiza, A. Niebylski; F. Moyano; N. M. Correa, R. D. Falcone. RSC Adv., 2017, 7, 5372–5380.


The Use of AOBH-DEHP Molecular Probe to Characterize BHDC Reverse Micelles Interfaces. Insights on the Interfacial Water Structure. M A. Crosio, J. J. Silber, F. Moyano, N. M. Correa, R. D. Falcone. ChemistrySelect, 2017, 2, 2880-2887 WILEY-VCH. Alemania. ISSN: 2365-6549.

-Papers 2016-

Determining the substrate permeability through the bilayer of large unilamellar vesicles of DOPC. A kinetic study. M. Alejandra Luna, Juana J. Silber, L. Sereno, N. Mariano Correa, Fernando Moyano. RSC Advances. 2016, 6, 62594 – 62601

Gold nanoparticles covalently assembled onto vesicle structures as possible biosensing platform. M. Fátima Barroso, M. Alejandra Luna, Juan S. Flores Tabares, Cristina Delerue-Matos, N. Mariano Correa, Fernando Moyano, Patricia G. Molina. Beilstein J. Nanotechnol., 2016, 7, 655-663

How the Type of Cosurfactant Impacts Strongly on the Size and Interfacial Composition in Gemini 12-2-12 RMs Explored by DLS, SLS, and FTIR Techniques. Victor E. Cuenca, R. Darío Falcone, Juana J. Silber, and N. Mariano Correa. J Phys. Chem. B, 2016, 120, 467-476.

A protic Ionic Liquid, when Entrapped in Cationic Reverse Micelles, Can Be Used as Suitable Solvent for a Bimolecular Nucleophilic Substitution Reaction. Matias A. Crosio, N. Mariano Correa, Juana J. Silber, R. Darío Falcone. Organic & Biomolecular Chemistry, 2016, 14, 3170-3177.

Effect of the Confinement on the Properties of Mixed Polar Solvents Sequestrated. The case of Enzymatic Catalysis Performed in Nonaqueous AOT Reverse Micelle. Andrés M. Durantini, R. Darío Falcone, Juana J. Silber, N. Mariano Correa. ChemPhysChem. 2016, 17, 1678 – 1685

Square Wave Voltammetry: An Alternative Technique to Determinate Piroxicam Release Profile from Nanostructured Lipid Carriers. 
Jessica Otarola, Mariano Garrido, N. Mariano Correa, Patricia G. Molina. ChemPhysChem, 2016, 17, 2322-2328

Electrochemical and Photophysical Behavior of 1-Naphthol in Benzyl-n-hexadecyldimethylammonium 1,4-bis (2-ethylhexyl) Sulfosuccinate Large Unilamellar Vesicles. 
Airam K. Cobo Solis, N. Mariano Correa, Patricia G. Molina. PhysChemChemPhys, 2016, 18, 15645-15653.

Nanoscale Control Over Interfacial Properties in Mixed Reverse Micelles Formulated Using Sodium 1,4-bis-2-ethylhexylsulfosuccinate and Tri-n-octyl Phosphine Oxide Surfactants.
 Emmanuel Odella, R. Dario Falcone, Juana J. Silber, N. Mariano Correa. ChemPhysChem. 2016, 17, 2407-2414.

Properties of AOT reverse micelle interfaces with different polar solvents.
 M. Alejandra Luna, N. Mariano Correa, Juana J. Silber, R. Dario Falcone, Fernando Moyano. Journal of Physical Organic Chemistry, 2016, 29, 580-585.

How the cation 1-butyl-3-methylimidazolium impacts on the interaction between the entrapped water and the reverse micelle interface created with an ionic liquid-like surfactant. C. Lépori, N. M. Correa, J. J. Silber, R. D. Falcone. Soft Matter, 2016, 12, 830-844.  

Non-aqueous Reverse Micelles Created with a Cationic Surfactant: Encapsulating Ethylene Glycol in BHDC/nonpolar solvent blends. F M. Agazzi, R. D. Falcone, J. J. Silber, N. M. Correa. Colloids and Surfaces A 2016, 509,467-473. 
  

-Papers 2015-
Impact of the polar core size and external organic media composition on the micelle-micelle interactions. Effect on gold nanoparticles synthesis. J. A. Gutierrez, M. A. Luna, N. M. Correa, J. J. Silber, R. D. Falcone. New Journal of Chemistry, 2015, 39, 8887-8895.

Singularities on the Physicochemical Properties of Spontaneous AOT-BHD Unilamellar Vesicles in Comparison with DOPC Vesicles. C. C. Villa, N. M. Correa, J. J. Silber, F. Moyano, R. D. Falcone. Phys.Chem.Chem.Phys., 2015, 17, 17112-17121.

On the Characterization of NaDEHP/n-Heptane Nonaqueous Reverse Micelles. Effect of the Polar Solvent. S. Quintana, R. D. Falcone, J.J. Silber, N. M. Correa, F. Moyano. Phys.Chem.Chem.Phys., 2015, 17, 7002-7011.

Droplet Droplet Interactions investigated using a Combination of Electrochemical and Dynamic Light Scattering Techniques. The Case of Water/BHDC/Benzene:n-Heptane System. J. S. Florez, N. Mariano Correa, Juana J. Silber, Leonides Sereno, Patricia G. Molina, Soft Matter, 2015, 11, 2952-2962.

Green Electrodes Modified With Au Nanoparticles Synthesized in Glycerol as Electrochemical Nitrite Sensor. D. Gobelli, N. M. Correa, M. F. Barroso, F. Moyano, P. G. Molina. Electroanalysis, 2015, 27, 1-10.

The Hydrolysis of Phenyl Trifluoroacetate in AOT/N-Heptane RMs as a Sensor of the Encapsulated Water Structure. O. Fernando Silva, Rita H. de Rossi, N. Mariano Correa RSC Advances, 2015, 5, 34878-34884.

-Papers 2014-
Spectroscopic and electrochemical studies of high-valent water soluble manganese porphyrine. Electrocatalytic water oxidation. María Alejandra Luna, Fernando Moyano, Leonides Sereno, Fabiana D´Eramo. Electrochimica Acta, 2014, 135, 301-310.

Effect of the Cationic Surfactant Moiety on the Structure of Water Entrapped in Two Catanionic Reverse Micelles Created from Ionic Liquid-Like Surfactants. Cristian C. Villa, Juana J. Silber, N. Mariano Correa, R. Darío Falcone. ChemPhysChem., 2014, 15 3097-3109.

How TOPO affects the interface of the novel mixed water/AOT:TOPO/n-heptane reverse micelles: dynamic light scattering and Fourier transform infrared spectroscopy studies. Emmanuel Odella, R. Darío Falcone, Juana J. Silbera, N. Mariano Correa. Phys.Chem.Chem.Phys., 2014, 16, 15457-15468.

The use of Two Non-Toxic Lipophilic Oils to Generate Environmentally Friendly Anionic Reverse Micelles Without Cosurfactant. Comparison with the Behavior Found for Traditional Organic Non-Polar Solvents. V.R. Girardi, J.J. Silber, N. Mariano Correa, R. Darío Falcone, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 457, 354-362.

Molecular Dynamics Simulation of Water/BHDC Cationic Reverse Micelles. Structural Characterization, Dynamical Properties, and Influence of Solvent on Intermicellar Interactions. Federico M. Agazzi, N. Mariano Correa, Javier Rodriguez. Langmuir, 2014, 30 (32), 9643-9653.

On the Investigation of the Droplet–Droplet Interactions of Sodium 1,4-Bis(2-ethylhexyl) Sulfosuccinate Reverse Micelles upon Changing the External Solvent Composition and Their Impact on Gold Nanoparticle Synthesis. J. A. Gutierrez, R. D. Falcone, M. A. Lopez-Quintela, D. Buceta, J. J. Silber, N. M. Correa. Eur. J. Inorg. Chem., 2014, 2014 (27), 2095–2102.
Inside Cover Picture in Special Issue: Coordination Chemistry 100 Years after Werner (Cluster Issue)






Supramolecular Assemblies Obtained by Mixing Different Cyclodextrins and AOT or BHDC Reverse Micelles. O. Fernando Silva, N. Mariano Correa, Juana J. Silber, Rita H. de Rossi, Mariana A. Fernández. Lanmguir, 2014, 30, 3354-3362.


Probing the Microenvironment of Unimicelles Constituted of Amphiphilic hyperbranched Polyethyleneimine using 1-methyl-8-oxyquinolinium Betaine. Agustin S. Picco, Gustavo F. Silbestri, R. Dario Falcone, Omar Azzaroni, Marcelo Ceolin, N. Mariano Correa. Phys.Chem.Chem.Phys., 2014, 16, 13458-13464. 

Ionic Liquids entrapped in reverse micelles as nanoreactors for SN2 reaction. Effect of the confinement on the chloride ion availability. D. Blach, M Pessêgo, J. J. Silber, N. M. Correa, L. García-Río, R. D. Falcone. Langmuir, 2014, 30, 12130-12137.

-Papers 2013-
Enzymatic Hydrolysis of N-Benzoyl-L-tyrosine p-nitroanilide by α-Chymotrypsin in DMSO-water/AOT/n-Heptane Reverse Micelles. A Unique Interfacial Effect on the Enzymatic Activity. Fernando Moyano, Evangelina Setien, Juana J. Silber, N. Mariano Correa. Langmuir, 2013, 29, 8245-8254.

More Evidences on the Control of the Reverse Micelles Sizes. Combination of Different Techniques as Powerful Tool to Monitor AOT reversed Micelles Properties. Andrés M. Durantini, R. Darío Falcone, Juana J. Silber, and N. Mariano Correa. J. Phys. Chem. B., 2013, 117, 3818-3828.

PRODAN Dual Emission Feature to Monitor BHDC Interfacial Properties Changes with the External Organic Solvent Composition. F. Agazzi, J. Rodriguez, R. D. Falcone, J. J. Silber, N. M. Correa. Langmuir, 2013, 29, 3556-3566.

An Interesting Case where Water Behaves as a Unique Solvent. 4-Aminophthalimide Emission Profile to Monitor Aqueous Environment. Andrés M. Durantini, R. Darío Falcone, Jorge D. Anunziata, Juana J. Silber, Elsa B. Abuin, Eduardo A. Lissi, N. Mariano Correa. J. Phys. Chem. B., 2013, 117, 2160-2168.

Electron Donor Ionic Liquids entrapped in Anionic and Cationic Reverse Micelles. Effect of the Interface on the Ionic Liquid-Surfactant Interactions Diana Blach, Juana J. Silber, N. Mariano Correa, R. Darío Falcone. Phys.Chem.Chem.Phys., 2013, 15, 16746-16757.

-Papers 2012-
A Unique Ionic Liquid with Amphiphilic Properties That Can Form Reverse Micelles and Spontaneous Unilamellar Vesicles. Cristian C. Villa, Fernando Moyano, Marcelo Ceolin, R. Dario Falcone, N. Mariano Correa. Chem. Eur. J., 2012, 18, 15598-15601.

Nonaqueous Polar Solvents in Reverse Micelle Systems. N. Mariano Correa, Juana J. Silber, Ruth E. Riter, Nancy E. Levinger. Chem. Rev. 2012, 12, 4569-4602.

C343 behavior in benzene/AOT reverse micelles. The role of the dye solubilization in the non-polar organic pseudophase. Jorge A. Gutierrez, R. Darío Falcone, Juana J. Silber, N. Mariano Correa. Dyes and Pigments. 2012, 95, 290-295.

The Effect of Different Interfaces and Confinement on the Structure of the Ionic Liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide Entrapped in Cationic and Anionic Reverse Micelles. Darıo D. Ferreyra, N. Mariano Correa, Juana J. Silber, R. Darıo Falcone. Phys.Chem.Chem.Phys., 2012, 14, 3460-3470.

Comparison between two Anionic Reversed Micelle Interfaces. The Role of Water-Surfactant Interactions on the Interface Properties. S. S. Quintana, R. D. Falcone, J. J. Silber, N. M. Correa. ChemPhysChem., 2012, 13, 115-123.

Inhibited Phenol Ionization in Reverse Micelles. Confinement Effect at the Nanometric Scale. O. Fernando Silva, Mariana Fernández, Juana J. Silber, Rita H. de Rossi, N. Mariano Correa. ChemPhysChem. 2012, 13, 124-130.

-Papers 2011-
Solvent Blends can Control Cationic Reversed Micellar Interdroplet Interactions. The Effect of n-Heptane:Benzene Mixture on BHDC Interfacial Properties: Droplet Sizes and Micropolarity. F. Agazzi, R.D. Falcone, J.J. Silber, N.M. Correa. J. Phys. Chem. B., 2011, 115, 12076-12084.

Electrochemistry in Large Unilamellar Vesicles. The distribution of 1-Naphthol studied by Square Wave Voltammetry. J. S. Florez Tabares, M. L. Blas, L. E. Sereno, J J. Silber, N. M. Correa, P. G. Molina. Electrochim. Acta, 2011, 56, 10231-10237.

A New Organized Media: Glycerol:N,N-Dimethylformamide/AOT/n-Heptane Reverse Micelles. A UV-Visible Absorption, Dynamic Light Scattering and 1HNMR Investigation. A M. Durantini, R.D. Falcone, J.J. Silber, N.M. Correa. J. Phys. Chem B., 2011, 15, 5894-5902.

Binding of o-nitroaniline to nonaqueous AOT reverse micelles. R. D. Falcone, J. J. Silber, M. A. Biasutti, N. M. Correa. ARKIVOK, 2011, 7, 369-379.

Layered structure of room temperature ionic liquids in microemulsions by multinuclear NMR spectroscopic studies. R. Dario Falcone, Bharat Baruah, Ernestas Gaidamauskas, Christopher D. Rithner, N. Mariano Correa, Juana J. Silber, Debbie C. Crans, Nancy E. Levinger. Chem. Eur. Journal. 2011, 17, 6837-6846.

Interfacial water with special electron donor properties: Effect of water-surfactant interaction in confined reversed micellar environments and its influence on the coordination chemistry of a copper complex. D. Blach, N.M. Correa, J.J. Silber, R.D. Falcone. J. Colloid Interface Sci., 2011, 355, 124-130.

-Papers 2010-
The Role of the Medium on the C343 Inter/Intramolecular Hydrogen Bond Interactions. An Absorption, Emission and 1HNMR Investigation of C343 in Benzene:n-Heptane Mixtures. J. A Gutierrez, R. D. Falcone, J. J. Silber, N. M. Correa. J. Phys. Chem. A., 2010, 114, 7326-7330.

Cationic Reverse Micelles Create Water with Super Hydrogen Bond Donor Capacity for Enzymatic Catalysis. Hydrolysis of 2-Naphthyl Acetate by a-Chymotrypsin. F. Moyano, J. C Mejuto, R. D. Falcone, J. J. Silber, N. M. Correa. Chem. Eur. J., 2010, 16, 8887-8893.

A kinetic study of the photodynamic effect on tryptophan methyl ester and tryptophan octyl ester in DOPC vesicles. A. Posadaz, N. M. Correa, M. A. Biasutti, N. A. Garcia. Photochem. Photobiol., 2010, 86, 96-103.

An Alternative Approach to Quantify Partition Process in Confined Environments: The Electrochemical Behavior of PRODAN in Unilamellar Vesicles. F. Moyano, P. G. Molina, J.J. Silber, L. Sereno, N.M. Correa. ChemPhysChem., 2010, 11, 236-244.

-Papers 2009-
Which are the Factors that Control the Nonaqueous AOT Reverse Micelles Sizes? A Dynamic Light Scattering Study. R.D. Falcone, J.J. Silber, N. M. Correa. Phys.Chem.Chem.Phys., 2009, 11, 11096-11100.

On the Formation of New Reverse Micelles: A Comparative Study of Benzene/Surfactants/Ionic Liquids Systems Using UV-Visible Absorption Spectroscopy and Dynamic Light Scattering. R. D. Falcone, N. M. Correa, J. J. Silber Langmuir, 2009, 25, 10426-10429.

Effect of Constrained Environment on the Interaction between the Surfactant and Different Polar Solvents Encapsulated Within AOT Reverse Micelles. A. M. Durantini, R. D. Falcone, J. J. Silber, N. M. Correa. ChemPhysChem., 2009, 10, 2034-2040.

Characterization of Multifunctional Reverse Micelles Interfaces Using Hemicyanines as Molecular Probes. 2: Effect of the Surfactant. S. S. Quintana, F. Moyano, R. D. Falcone, J. J. Silber, N. M. Correa. J. Phys. Chem. B., 2009, 113, 6718-6724.

Characterization of Multifunctional Reverse Micelles Interfaces Using Hemicyanines as Molecular Probes. 1: Effect of the hemicyanines Structure. F. Moyano, S. S. Quintana, R. D. Falcone, J. J. Silber, N. M. Correa. J. Phys. Chem. B., 2009, 113, 4284-4292.

-Papers 2008-
An Example of How to Use AOT Reverse Micelles Interface to Control a Photoinduced Intramolecular Charge Transfer Process. M. Novaira, F. Moyano, M. A. Biasutti, J. J. Silber, N. M. Correa. Langmuir, 2008, 24, 4637-4646.

On the Investigation of the Bilayer of Large Unilamellar Vesicles Using Different Cationic Hemicyanines and DPH. A Wavelenght – Selective Fluorescense Approach. F. Moyano, J. J. Silber, N. M. Correa. J. Colloid Interface Sci., 2008, 317, 332-345.

Kinetics of reactions catalyzed by enzymes in solutions of surfactants. M. A. Biasutti, E. A. Abuin, J. J. Silber, N. M. Correa, E. A. Lissi. Review, Advances in Colloid and Interface Science., 2008, 136, 1-24.

-Papers 2007-
On the possibility that cyclodextrins chiral cavities can be available on AOT n-heptane reverse micelles. A UV-Visible and Induced Circular Dichroism Study. F. O. Silva, J. J. Silber, R. H. de Rossi, N. M. Correa, M. A. Fernández. J. Phys. Chem. B., 2007, 111, 10703-10712.

Electrochemistry in AOT Reverse Micelles. A Powerful Technique to Characterize Organized Media. Patricia G. Molina, Juana J. Silber, N. Mariano Correa, Leonides Sereno. J. Phys. Chem C., 2007, 111, 4269-4276.

Comparative Study of the Photophysical Behaviour of Fisetin in Homogeneous Media and in Anionic and Cationic Reverse Micelles Media. Matías Funes, N. Mariano Correa, Juana J. Silber, M. Alicia Biasutti. Photochem. Photobiol., 2007, 83, 486-493.   

New Insights on the Photophysical Behavior of PRODAN in Anionic and Cationic Reverse Micelles. From Which State or States does it Emit?. M. Novaira, M. A. Biasutti, J. J. Silber, N. M. Correa. J. Phys. Chem B., 2007, 111, 748-759.

-Papers 2006-
Using Kamlet-Taft solvent descriptors to explain the reactivity of anionic nucleophiles in ionic liquids. Lorna Crowhurst, Ruben Falcone, N. Llewellyn Lancaster, Veronica Llopis -Mestre, Tom Welton. J. Org. Chem., 2006, 71, 8847-8853.

When water is not water?. Exploring water confined in reverse micelles using a highly charged inorganic molecular probe. B. Baruah, J. Roden, M. Sedgwick, N. M. Correa, D. C. Crans N. E. Levinger. J. Am. Chem. Soc., 2006, 128, 12758-12765.

Non-aqueous reverse micelles media for the SNAr reaction between 1-fluoro-2,4-dinitrobenzene and piperidine. N. M. Correa, E. N. Durantini, J. J. Silber. J. Phys. Org. Chem., 2006, 19, 805-812.

What can you learn from a molecular probe?. New insights on the behavior of C343 in homogeneous Solutions and AOT reverse micelles. N. M Correa, N. E. Levinger. J. Phys. Chem. B., 2006, 110, 13050-13061. 

New Insights on the Behavior of Prodan in Homogeneous Media and in Large Unilamellar Vesicles. F. Moyano, M. A. Biasutti, J. J. Silber, N. M. Correa. J. Phys. Chem. B. 2006, 110, 11838-11846.

The Use of Acridine Orange Base (AOB) as Molecular Probe to Characterize Non-aqueous AOT Reverse Micelles. R. Darío Falcone, N. Mariano Correa, M. Alicia Biasutti, Juana J. Silber. J. Colloid Interface Sci., 2006, 296, 356-364.

-Papers 2005-
The Real Structure of Formamide Entrapped by AOT Non Aqueous Reverse Micelles. FT-IR and 1HNMR Studies. N. M. Correa, P. A. R. Pires, J. J. Silber, O. El Seoud. J. Phys. Chem. B., 2005, 109, 21209-21219.

Distribution of amines in water/AOT/n-hexane reverse micelles. Influence of the amine chemical structure. L. Zingaretti, N. M. Correa, L. Boscatto, S. M. Chiacchiera, E. N. Durantini, S. G. Bertolotti, C. R. Rivarola, J. J. Silber. J. Colloid Interface Sci., 2005, 286, 245-252.

Characterization of Different Reverse Micelles Interfaces using The Reaction of 4-fluoro-3-nitrobenzoate with Piperidine. N. M. Correa, E. N. Durantini, J. J. Silber. J. Phys. Org. Chem., 2005, 18, 121-127.


Capítulos en libros / Chapters in books
  
Ionic Liquids in Soft Confinement. Effect of the Different Reverse Micelles Interfaces on the Entrapped Ionic Liquid Structure. R. D. Falcone, N. M. Correa, N. E. Levinger, J. J. Silber Capitulo del libro Ionic Liquid-Based Surfactant Science: Formulation, Characterization and Applications, Eds. Bidyut K. Paul and Satya P. Moulik, John Wiley & Sons Inc., USA. ISBN-10: 1118834194. ISBN-13: 9781118834190. 2015, 283-301.

Electro-optics and Electroporation of Synthetic Lipid Vesicles Z A Schelly, N. Asgharian, N. M. Correa, V. Peikov, S. Wu, H. Zeng, H. Zhang in Molecular and Colloidal Electro-optics," Capitulo 12 edited by Professors S. P. Stoylov and M. Stoimenova; CRC Press, Boca Raton, FL ISBN: 0-8493-9811-8 paginas 301-306. (2006).

Reactividad y Catálisis en Micelas Inversas. M.A. Biasutti, N.M. Correa, J.J. Silber.. under the sponsorship of IUPAC (Project 2002-064-1-300)- and INCA-Italy. Eds Rita H. de Rossi and Pietro Tundo- ISBN 88-88214-16-X. Química Verde en Latinoamerica. GREEN CHEMISTRY SERIES 239-258 (2004).

Solubilización y Reactividad en Soluciones Organizadas. N. Mariano Correa, M.A. Biasuti, J.J. Silber. Capítulo de libro Química Sustentable por invitación Editor: N. Nudelman. UNL. ISBN. 987-508-243-0. 269-294 (2004).

Study of Different Molecular Probes in Nonaqueous AOT Reverse Micelles. R.D. Falcone, N. Mariano Correa, M.A. Biasutti, J.J. Silber. Capítulo de libro de First- Italia-Argentina Workshop on Green Chemistry. Green Chemistry Series N 8. Eds G. Cerichelli, P. Tundo INCA. 71, ISBN 88-88214-03-8. Pag.71 – 73. (2003). 

Molecular Interactions in Reverse Micelles. M. A. Biasutti, N.M. Correa, J.J. Silber. Current Topics in Colloid and Interface Science. Research Trends. India Eds. F.M. Goñi, H. Hoffmann. Vol. 3, 35-51. ISBN 81-258-0045-X. (1999).